| EPSRC Reference: |
GR/L91719/01 |
| Title: |
FAR-IR RAIRS OF METAL-MOLECULE BONDING:REALISTIC MODELS OF TECHNOLOGICALLY IMPORTANT INTERFACES |
| Principal Investigator: |
Russell, Professor A |
| Other Investigators: |
|
| Researcher Co-Investigators: |
|
| Project Partners: |
|
| Department: |
Sch of Chemistry |
| Organisation: |
University of Southampton |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 October 1998 |
Ends: |
30 June 2002 |
Value (£): |
117,293
|
| EPSRC Research Topic Classifications: |
|
| EPSRC Industrial Sector Classifications: |
| No relevance to Underpinning Sectors |
|
|
| Related Grants: |
|
| Panel History: |
|
|
Summary on Grant Application Form |
|
This proposal aims to upgrade and develop the SRS Far-IR 13.3 beamline at Daresbury Laboratory in order to directly monitor the vibrations of molecule-metal bonds which play a pivotal role in determining the performance of an interface. The project will concentrate on interfaces relevant to fuel cell eletrocatalysis and in heterogeneous enantioselective catalysis. In both cases the following research strategy will be employed: i) Investigation of model interfaces, constructed in ultra-high vacuum conditions, to closely mimic the real interface. The complexity of the model interface will be increased in a step-wise fashion in order to directly establish the nature of molecule-metal and molecule-molecule interactions, and their perturbation by coadsorbed modifiers such as ions and solvent molecules which are known to play an important part in interface performance, ii) Investigation of realistic interfaces created by transfer into an environmental chamber in which the surface is subject to liquid environment.
|
|
Key Findings |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
|
Potential use in non-academic contexts |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
|
Impacts |
|
| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
|
| Date Materialised |
|
|
|
|
Sectors submitted by the Researcher |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
| Project URL: |
|
| Further Information: |
|
| Organisation Website: |
http://www.soton.ac.uk |