| EPSRC Reference: |
GR/K14377/01 |
| Title: |
DEHYDROGENATED FORMS OF ARENES AND HETERAROMATICS IN METAL CLUSTERS. |
| Principal Investigator: |
Deeming, Professor A |
| Other Investigators: |
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| Department: |
Chemistry |
| Organisation: |
UCL |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 November 1994 |
Ends: |
31 December 1997 |
Value (£): |
150,450
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| EPSRC Research Topic Classifications: |
| Chemical Synthetic Methodology |
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Summary on Grant Application Form |
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New dehydrogenated forms of arenes and heterocycles (x) and trinuclear and tetranuclear clusters, such as n3H(PPH2) (m3-x) (CO)9 and Ru4 (Pph)(m4-x) (CO)11, will be synthesised. Coordination geometries and dynamics of the m3 and m4 ligands X will show how tilted, vertical parallel, perpendicular or diagonal ligand orientations depends upon arene substituents or heterocycles used. Structure-reactivity relationships and the conversion of aromatic into non-aromatic systems will be examined.
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Key Findings |
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Potential use in non-academic contexts |
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Impacts |
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| Description |
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| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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