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Details of Grant 

EPSRC Reference: GR/T04472/01
Title: RAIS: Preparation of novel heterogenous catalysts using high temperature crystallisation
Principal Investigator: Hutchings, Professor G
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Chemtura
Department: Chemistry
Organisation: Cardiff University
Scheme: RAIS
Starts: 01 January 2004 Ends: 31 December 2004 Value (£): 33,610
EPSRC Research Topic Classifications:
Catalysis & Applied Catalysis
EPSRC Industrial Sector Classifications:
Chemicals
Related Grants:
Panel History:  
Summary on Grant Application Form
By applying low to moderate pressure (ambient - 150 bar) and temperature (upto 400 degrees) it is possible to prepare novel phases of V5+ and V4+ phosphate materials. This approach to synthesis is to be extended to other transition metal containing phosphate systems to preparre novel phases from amorphous precursor species which are to be tested as oxidation catalysts using hydrogen peroxide and molecular oxygen as the terminal oxidants. The phosphate systems to be investigated will include Ti, Cr, Mn, Fe, Ce, W, Zr and combined Zr/W phosphate materials. This study will also include an investigation into novel ZrSiO4 materials (based on the mineral zircon) with a view to preparing and characterising further novel selective oxidation catalysts.
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Organisation Website: http://www.cf.ac.uk