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Details of Grant 

EPSRC Reference: GR/S97521/01
Title: Surface supramolecular assembly: molecular entrapment & nanostructure fabrication
Principal Investigator: Champness, Professor NR
Other Investigators:
O'Shea, Dr JN Beton, Professor P
Researcher Co-Investigators:
Project Partners:
Department: Sch of Chemistry
Organisation: University of Nottingham
Scheme: Standard Research (Pre-FEC)
Starts: 01 October 2004 Ends: 31 March 2008 Value (£): 296,425
EPSRC Research Topic Classifications:
Chemical Synthetic Methodology Surfaces & Interfaces
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
Related Grants:
Panel History:  
Summary on Grant Application Form
We have recently demonstrated a major advance in surface based self-assembly which links supramolecular organisation to nanostructure fabrication. In this work a hydrogen-bonded supramolecular assembly is used to template nanostructure formation on a semiconductor surface. We now propose a wide ranging programme to establish the design rules which control the dimensions, architecture and stability of related two-dimensional supramolecular arrays and investigate the range of materials which may be successfully templated into nanostructures such as quantum dots. This will be achieved through the design and synthesis of appropriate component molecules which will be processed into two dimensional assemblies through sublimation and will be investigated using scanning tunnelling microscopy (STM) and photoelectron spectroscopy (XPS).
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Organisation Website: http://www.nottingham.ac.uk