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Details of Grant 

EPSRC Reference: GR/S72610/01
Title: New Catalyst Families Based on Bulky Metallocalixarene Substituents
Principal Investigator: Redshaw, Professor C
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: University of East Anglia
Scheme: Overseas Travel Grants Pre-FEC
Starts: 01 July 2004 Ends: 30 June 2005 Value (£): 10,250
EPSRC Research Topic Classifications:
Chemical Synthetic Methodology
EPSRC Industrial Sector Classifications:
Chemicals
Related Grants:
Panel History:  
Summary on Grant Application Form
The central thrust of this science will be to engineer new metallocalixarene catalysts with well defined structures for use in olefin polymerisation. These new calixarene species will be assembled from smaller ligands incorporating many of the desired structural features which have recently been shown to stabilise highly active metal centres in other catalytic systems.Novel calixarene ligands will be prepared in Japan and their coordination chemistry studied at UEA.Screening of all promising compounds will initially involve schienk-line tests (1 bar) in the presence of suitable aluminium activators to the determine 'ball-park' activity of the catalyst prior to any systematic study of the effect of pressure, co-catalyst, temperature etc...
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Organisation Website: http://www.uea.ac.uk