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Details of Grant 

EPSRC Reference: GR/S22547/01
Title: Hydrothermal Chemistry of Scandium : A Route to Novel Microporous Solids
Principal Investigator: Wright, Professor PA
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: University of St Andrews
Scheme: Standard Research (Pre-FEC)
Starts: 01 October 2003 Ends: 30 September 2006 Value (£): 77,864
EPSRC Research Topic Classifications:
EPSRC Industrial Sector Classifications:
Chemicals No relevance to Underpinning Sectors
Related Grants:
Panel History:  
Summary on Grant Application Form
Novel scandium phosphates, phosphonates and silicates will be prepared via hydrothermal syntheses in the presence of inorganic and/or organic templating agents where appropriate. Scandium possesses very promising properties as a framework forming element, but has previously been largely overlooked due to cost. New sources of commercially available scandium open up the possibility of extended research. As a part of the project the speciation of scandium in a range of aqueous solutions will be examined. The resultant microporous solids will be structurally characterised by single crystal and powder X-ray diffraction, solid state NMR (scandium-45 possesses favourable NMR properties) and high resolution electron microscopy and electron diffraction. The potential utility of scandium-containing solids as selective cation exchangers and molecular sieves will be measured.
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Organisation Website: http://www.st-and.ac.uk