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Details of Grant 

EPSRC Reference: GR/S21557/01
Title: On-line Ultra Trace Gas Analysis using Proton Transfer Reaction Mass and Electron Swarm Spectrometers
Principal Investigator: Mayhew, Professor C
Other Investigators:
Tuckett, Professor RP
Researcher Co-Investigators:
Project Partners:
Department: School of Physics and Astronomy
Organisation: University of Birmingham
Scheme: Standard Research (Pre-FEC)
Starts: 12 January 2004 Ends: 11 January 2007 Value (£): 209,631
EPSRC Research Topic Classifications:
Analytical Science Gas & Solution Phase Reactions
EPSRC Industrial Sector Classifications:
Aerospace, Defence and Marine Chemicals
Environment Food and Drink
Healthcare Pharmaceuticals and Biotechnology
Water No relevance to Underpinning Sectors
Related Grants:
Panel History:
Panel DatePanel NameOutcome
11 Dec 2002 Chemistry Prioritisation Panel (Science) Dec 02 Deferred
Summary on Grant Application Form
An ever-increasing need exists for high levels of sensitivity (ppbv - pptv) and chemical specificity to detect trace compounds in highly complex samples in real time. Examples include environmental science (e.g. waste management and pollution monitoring), defence (detection of explosives and chemical warfare agents), health and safety (e.g. monitoring factory air), and in the food processing area (e.g. monitoring food freshness). In meeting this need, some of the most promising approaches that have been developed are based on proton transfer to trace compounds by gas-phase ion-molecule reactions, or on the negative ionisation of a compound by gas-phase electron attachment. The overall success and general applicability of these approaches have been limited because of the lack of data on and an inadequate understanding of the elementary processes involved. Thus, instruments used for trace gas detection are not being exploited to their full potential. The PTR-MS and electron swarm apparatus offer rapid, very high sensitivity to trace gases. We wish to use our novel instruments to investigate thermal electron attachment to and ion reactions with trace gases. This includes the provision of data on the reaction and attachment rate coefficients and product ions for the various processes so that trace gases can be identified and concentrations in a particular environment readily quantified. Furthermore, we wish to explore the development of our apparatus for in-situ measurements of trace gases.
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Organisation Website: http://www.bham.ac.uk