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EPSRC Reference: GR/S08343/01
Title: ESR spectroscopy of the highly frustrated and low-dimensional magnetic systems
Principal Investigator: Petrenko, Dr OA
Other Investigators:
Researcher Co-Investigators:
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Department: Physics
Organisation: University of Warwick
Scheme: First Grant Scheme Pre-FEC
Starts: 05 August 2003 Ends: 04 August 2005 Value (£): 119,284
EPSRC Research Topic Classifications:
Materials Characterisation
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
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Panel History:  
Summary on Grant Application Form
The dynamics of magnetic excitations in highly frustrated and low-dimensional magnetic systems will be studied by means of Electron Spin Resonanc spectroscopy. In order to carry out such measurements a wide frequency range ESR spectrometer will be built. The list of crystals I propose to investigate includes the following: 1) CuFe02, quasi two-dimensional antiferromagnet on a triangular lattice, which exhibits as many as five unexplained spin-flop like magnetisation anomalies in an applied magnetic field; 2) pure and doped Tb2Ti2O7, a magnet on a pyrochlore lattice, which could be described as a spin-liquid; 3) molecular magnets (5CAP)2CuCl4 and (5MAP)2CuCl4, two-dimensional square-lattice Heisenberg antiferromagnets witl weak exchange interactions.In CuFe02, the magnetic resonance will be studied to examine the magnetic phase transition and to establish the relative importance of the various magnetic interactions that are present in this system. In Tb2Ti2O7, ESR spectroscopy should help to verify whether or not an external field changes tt range of the magnetic correlations and to establish the influence of further-neighbour interactions on the ground state formation. In the molecular magnets, the ESR spectrum will be investigated in order to observe the theoretically predicted instability of the magnetic excitations in strong magneti fields, where the spin waves become unstable with respect to spontaneous two-magnon decay.
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Organisation Website: http://www.warwick.ac.uk