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Details of Grant 

EPSRC Reference: GR/R94671/01
Title: Mechanochemistry: dislocations and their mesoscopic and microscopic interactions with impurities
Principal Investigator: Heggie, Professor MI
Other Investigators:
Researcher Co-Investigators:
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Department: Chemistry
Organisation: University of Sussex
Scheme: ROPA
Starts: 01 February 2003 Ends: 31 January 2005 Value (£): 119,431
EPSRC Research Topic Classifications:
Chemical Structure Materials Characterisation
EPSRC Industrial Sector Classifications:
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Panel History:  
Summary on Grant Application Form
Dislocations control plastic behaviour. Impurities can interact strongly with them - not simply as precipitates but even in more homogeneous distributions. In addition to their role in pinning dislocations, impurities may create dislocations when they condense (e.g. in the case of H in Si). This could have profound consequences for sudden loss of brittleness and it should be generic ( extending to H2O in quartz, HF in ice and H in diamond). Other impurity interactions could give rise to novel chemical reactions within dislocation cores. First principles calculations and elasticity theory analysis will be applied to establish these 'mechanochemical' effects.
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Organisation Website: http://www.sussex.ac.uk