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EPSRC Reference: GR/R72297/01
Title: Intramolecular Dynamical Sudies using an Imaging Photoelectron Spectrometer
Principal Investigator: Reid, Professor K. L.
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Sch of Chemistry
Organisation: University of Nottingham
Scheme: Standard Research (Pre-FEC)
Starts: 01 July 2002 Ends: 30 June 2005 Value (£): 244,131
EPSRC Research Topic Classifications:
Chemical Structure
EPSRC Industrial Sector Classifications:
Chemicals
Related Grants:
Panel History:  
Summary on Grant Application Form
In this work we propose to build on our existing expertise in the measurement of photoelectron angular distributions (PADS) and develop a spectrometer in which the angular distributions are measured as a snapshot on an imaging detector which will simultaneously discriminate photoelectrons by their time of arrival. This new spectrometer will improve the collection efficiency of our experiment by a factor of around 1000. The spectrometer will be extensively tested by comparison with results from our existing field-free time-of-flight photoelectron spectrometer whose detector subtends a small solid angle and in which PADS are measured b3 rotating the polarization of the ionizing light - one angle at a time. The spectrometer will then be used to monitor intramolecular vibrational energy redistribution, isomerization and internal conversion processes in polyatomic molecules such as toluene, stilbene and acetylene.
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Organisation Website: http://www.nottingham.ac.uk