| EPSRC Reference: |
GR/R27471/01 |
| Title: |
New Catalysts For the Hydrocracking of High RMM Fractions of Coal Derived Liquids and Heavy Hydrocarbon Liquids |
| Principal Investigator: |
Kandiyoti, Professor R |
| Other Investigators: |
|
| Researcher Co-Investigators: |
|
| Project Partners: |
|
| Department: |
Chemical Engineering |
| Organisation: |
Imperial College London |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 December 2001 |
Ends: |
30 November 2004 |
Value (£): |
110,715
|
| EPSRC Research Topic Classifications: |
| Catalysis & Applied Catalysis |
Coal Technology |
| Oil & Gas Extraction |
|
|
| EPSRC Industrial Sector Classifications: |
| Chemicals |
Energy |
| No relevance to Underpinning Sectors |
|
|
| Related Grants: |
|
| Panel History: |
|
|
Summary on Grant Application Form |
|
Difficulties in hydrocracking the high molecular mass fraction of coal derived liquids into lighter products, such as transport fuels, remains a major obstacle to the commercialisation of coal liquefaction technology. Similar problems with the processing of heavy residues limit the economic return from petroleum refining. Recent collaboration between the proposers, at Imperial and Aston, now suggests an exciting advance in this hydrocracking step with the use of novel pillared clay catalysts. These new materials out-perform existing commercial catalysts, particularly in their effectiveness and resistance to deactivation. The propose project comprises three components: catalyst synthesis (Aston), catalyst characterisation (Birmingham) and catalyst testing (Aston, Imperial) with a variety of petroleum, coal and also bio-mass derived heavy fractions. The scale-up of the syntheses of the currently successful catalysts will be developed from the bench to larger scale in a purpose built reactor. Further new catalysts will be prepared using conventional ion exchange techniques and also microwave driven reactions. Catalyst characterisation work will focus on the solid-state chemistry aspects of the catalysts and their precursors. Characterisation of the solids before and after use will be correlated with their catalytic properties. The aim will be the design of more selective, effective and robust catalysts. Hydrocracking reactives of the new catalysts will be measured in a microbomb reactor (Imperial), at temperatures up to 450 C and pressures up to 200 bar, and in a microwave reactor (Aston) under more moderate conditions. The extent of hydrocracking achieved Mil be estimated by a suite of analytical techniques including SEC for molecular mass distribution, UVF spectrroscopy for aromatic cluster size determination and NMR spectroscopy for detecting PNA-ring structural changes. The latter technique will be the subject of particular study
|
|
Key Findings |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
|
Potential use in non-academic contexts |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
|
Impacts |
|
| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
|
| Date Materialised |
|
|
|
|
Sectors submitted by the Researcher |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
| Project URL: |
|
| Further Information: |
|
| Organisation Website: |
http://www.imperial.ac.uk |