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Details of Grant 

EPSRC Reference: GR/R11315/01
Title: Ropa: Elasticity and Mechanical Relaxation In Chiral Biopolymer Networks
Principal Investigator: Terentjev, Professor E
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Physics
Organisation: University of Cambridge
Scheme: ROPA
Starts: 01 November 2001 Ends: 30 April 2004 Value (£): 138,810
EPSRC Research Topic Classifications:
Cells Complex fluids & soft solids
EPSRC Industrial Sector Classifications:
Healthcare Pharmaceuticals and Biotechnology
Related Grants:
Panel History:  
Summary on Grant Application Form
This project will focus on experimental study of equilibrium and dynamic elastic properties of elastomeric networks of chiral twist-storing polymers: natural polypeptides and synthetic. Theoretical research, being carried out in parallel and a little ahead of this work, suggests that the elastic response of such networks should be highly non-classical, dominated by enthalpic effects of writhe superhelix formation and other non-trivial topological constraints characteristic of chiral polymers. We shall perform a detailed high-precision dynamic-mechanical study of this elastic response and correlate it with optical rotation data showing the degree of macroscopic helicity in the material, aiming to establish universal relations that unite chiral biological and synthetic polymer networks and contrast them with classical centrosymmetric rubbers.
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Organisation Website: http://www.cam.ac.uk