| EPSRC Reference: |
GR/R09329/01 |
| Title: |
Coordination Approaches To Multimetal, Multiporphyrin Arrays |
| Principal Investigator: |
Sanders, Professor J |
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| Department: |
Chemistry |
| Organisation: |
University of Cambridge |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
09 April 2001 |
Ends: |
08 April 2003 |
Value (£): |
126,945
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Summary on Grant Application Form |
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We propose a new co-ordination approach to the synthesis of multimetal, multiporphyrin arrays. This will employ metalloporphyrin monomers which are themselves ligands for different metalloporphyrins: all building blocks will be complementary in co-ordination chemistry and geometry, allowing the unambiguous and quantitative build-up of heterometallic systems in one synthetic step from monomers. These arrays should possess vectorial photophysical and electrochemical gradients which may be of interest in devices. The same co-ordination approach should yield new large species with cavities in short synthetic sequences. This approach is complementary to the long sequences which lead to all-covalent porphyrin aligomers and dendrimers, and can also be combined with the covalent route.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.cam.ac.uk |