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Details of Grant 

EPSRC Reference: GR/R08254/01
Title: Physical Characterisation of Molecular and Extended Inorganic Solids
Principal Investigator: Greaves, Professor C
Other Investigators:
Douthwaite, Dr R Constable, Professor EC Wright, Dr AJ
Anderson, Professor PA Muirhead, Dr CM Pikramenou, Professor Z
Abell, Professor JS Abell, Professor J Housecroft, Professor CE
Hriljac, Dr J
Researcher Co-Investigators:
Project Partners:
Elliot Scientific Ltd University of Birmingham
Department: School of Chemistry
Organisation: University of Birmingham
Scheme: JREI
Starts: 22 November 2001 Ends: 21 November 2004 Value (£): 103,320
EPSRC Research Topic Classifications:
Materials Characterisation
EPSRC Industrial Sector Classifications:
Electronics
Related Grants:
Panel History:  
Summary on Grant Application Form
Research is aimed at investigating the physical characteristics of a wide range of inorganic materials and investigating correlations between physical, structural and chemical properties. Conductivity measurements will be performed, in fields up to 7T, on mixed metal manganese oxides and various thiospinels with potentially useful magnetoresistance properties. The conductivities of zeolites containing conductive polymers will also be determined and related structural features. Magneticv measurements will play an important role in the characterisation of magnetoresistances materials, but will also be essential for detecting superconducting transitions in our search for new and modified high-Tc phases, and for examining exchange interactions in extended inorganic phases. The magnetic properties of a variety of molecular systems will be studied, including those near the border between high-spin and low-spin behaviour. High nuclearity metallodendrimers and metal oxides nanoparticles will also be studied. Thin films of certain metallodendrimers, and single crystals of thiospinels will be studied using the torque magnetometer to determine anisotropic magnetic effects. The thermoelectric properties of a range of materials will be studied as part of the collaboration with Quantum Design (for optimisation of the new probe) and to explore the possibility of designing new materials with potential for thermoelectric cooling and heating devices.
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Further Information:  
Organisation Website: http://www.bham.ac.uk