| EPSRC Reference: |
GR/N09459/01 |
| Title: |
NEW CATALYSTS FOR HIGH ACTIVITY C-X BOND FORMATION UNDER FLUOROUS BIPHASIC CONDITIONS |
| Principal Investigator: |
Bedford, Professor RB |
| Other Investigators: |
|
| Researcher Co-Investigators: |
|
| Project Partners: |
|
| Department: |
Chemistry |
| Organisation: |
University of Exeter |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
02 October 2000 |
Ends: |
01 October 2003 |
Value (£): |
66,313
|
| EPSRC Research Topic Classifications: |
| Catalysis & Applied Catalysis |
|
|
| EPSRC Industrial Sector Classifications: |
| Chemicals |
Pharmaceuticals and Biotechnology |
| No relevance to Underpinning Sectors |
|
|
| Related Grants: |
|
| Panel History: |
|
|
Summary on Grant Application Form |
|
We will synthesise new perfluoroalkylated phosphite, phosphinite and phosphonite ligands that can undergo orthopalladation. The new palladium complexes will be structurally related to non-perfluoralkylated analogues that we have previously synthesised that show the highest activities yet reported in the Suzuki, Stille and Heck reactions. The new orthopalladated perfluoralkyl substituted phosphite, phosphinite and phosphonite complex are expected not only to show comparable activity, but should also be amenable to recycling using fluorous biphasic separation. Such a recycling technique has not yet been reported for Heck type chemistry.
|
|
Key Findings |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
|
Potential use in non-academic contexts |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
|
Impacts |
|
| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
|
| Date Materialised |
|
|
|
|
Sectors submitted by the Researcher |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
| Project URL: |
|
| Further Information: |
|
| Organisation Website: |
http://www.ex.ac.uk |