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Details of Grant 

EPSRC Reference: GR/M51215/01
Title: ROPA: A REMARKABLE NEW MECHANISM FOR METAL CATALYSED ENANTIOSELECTIVE HYDROGENATION?
Principal Investigator: Heaton, Professor B
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: University of Liverpool
Scheme: ROPA
Starts: 01 April 1999 Ends: 31 March 2000 Value (£): 65,485
EPSRC Research Topic Classifications:
Catalysis & Applied Catalysis
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
Related Grants:
Panel History:  
Summary on Grant Application Form
The presently unique HPNMR flow cell will be used in conjunction with HPIR spectroscopy, to detect intermediates and elucidate the mechanism of the Ru-catalysed asymmetric hydrogenation of ketones (at<50 atm H2). Cationic rhodium complexes of the type trans-[RhCl2(LL)(L'L')]+(LL=PR3 or diphosphine; L'L'= diamine) will also be prepared with achiral/chiral ligands in order to perform analogous to test their hydrogenation activity and 'in situ' spectroscopic measurements will be used to characterise their mechanisms of hydrogenation.
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Organisation Website: http://www.liv.ac.uk