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Details of Grant 

EPSRC Reference: GR/M44972/02
Title: ROPA: REACTIVITY CONTROL THROUGH LIGAND DESIGN
Principal Investigator: Bochmann, Professor M
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: University of East Anglia
Scheme: ROPA
Starts: 01 March 2000 Ends: 31 May 2001 Value (£): 64,993
EPSRC Research Topic Classifications:
Chemical Synthetic Methodology
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
Related Grants:
Panel History:  
Summary on Grant Application Form
The effect of tailoring coordination pockets by using new sterically hindered ni-and tridentate donor ligands on the reactivity of complexes of di-and trivalent metals will be studied, including parameters such as substituent rigidity, chelate ring size, charge, and donor strength. Ligand types will include polydentate imines and pyrrols, phosphoranimines, and anionic phosphorus ylids. The latter will be designed to alllow a new mode of stereocontrol. A particular target will be cationic lanthanide complexes and an assessment of their potential as alkene polymerisation catalysts.
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Organisation Website: http://www.uea.ac.uk