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Details of Grant 

EPSRC Reference: GR/M40837/01
Title: INORGANIC MATERIALS WITH COMPLEX FORM: MORPHOSYNTHESIS OF CALCIUM CARBONATE MICRO-SPONGES
Principal Investigator: Mann, Professor S
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: University of Bristol
Scheme: Standard Research (Pre-FEC)
Starts: 01 October 1999 Ends: 30 September 2002 Value (£): 231,954
EPSRC Research Topic Classifications:
Materials Characterisation Materials Synthesis & Growth
EPSRC Industrial Sector Classifications:
Chemicals Healthcare
No relevance to Underpinning Sectors
Related Grants:
Panel History:  
Summary on Grant Application Form
Inorganic materials with complex morphological forms might have important practical uses as light weight fillers, pigments, filters, sorbents for gases and liquids, as well as biodegradable materials for the controlled storage and release of functional molecules. We propose to develop a novel facile one-step, high-yield approach to the preparation of spheroidal micron-sized particles of porous calcium carbonate. Inorganic micro-sponges will be prepared by mineralisation at the anionic headgroups of sodium dodecylsulfate molecules present in the oil/water droplet interface. The size of the mineral spheroids will be controlled by the diameter of the water droplets, which in turn will be controlled by the composition of the microemulsion. A secondary patterning process, involving the imprinting of mineralization around micro-bubbles of CO2 entrapped within and at the surface of the water droplets, will be used to generate an elaborate sponge-like texture in the vaterite spheroids. Potential applications of the micro-sponges, such as filler, optical brightners (pigments), micro-capillary devices (inks, dyes) and colloidal stabilisers, will be investigated.
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Organisation Website: http://www.bris.ac.uk