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EPSRC Reference: GR/M29528/01
Title: DESIGN AND SYNTHESIS OF PORPHYRAZINE-FULLERENE COMPLEXES: NOVEL MOLECULAR MAGNETS
Principal Investigator: Barrett, Professor T
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: Imperial College London
Scheme: ROPA
Starts: 10 May 1999 Ends: 09 May 2001 Value (£): 104,438
EPSRC Research Topic Classifications:
Chemical Synthetic Methodology Materials Synthesis & Growth
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
Related Grants:
Panel History:  
Summary on Grant Application Form
The objectives of this research are the design and synthesis of charge transfer complexes derived from the reaction of fullerenes C60 and C70 with [2,3,7,8,12,13,17,18-octakis (dimethylamino)porphyrazinato]chromium(II), -mangenese(II), tin(II), etc or from the reaction of fullerides such as K3C60 with related chromium(iii), manganese(III), tin(IV) porphyrazine complexes. These complexes are proposed to exhibit molecular ferromagnetic properties with higher Tc than the C60 complex with tetrakis(dimethylamino)ethene.
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Organisation Website: http://www.imperial.ac.uk