| EPSRC Reference: |
GR/M10465/01 |
| Title: |
CATALYTIC CHEMISTRY OF HIGHER OLEFINS SUPERITICAL CARBON DIOXIDE |
| Principal Investigator: |
Xiao, Professor J |
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| Department: |
Chemistry |
| Organisation: |
University of Liverpool |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 October 1998 |
Ends: |
30 September 2001 |
Value (£): |
139,743
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| EPSRC Research Topic Classifications: |
| Catalysis & Applied Catalysis |
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| EPSRC Industrial Sector Classifications: |
| No relevance to Underpinning Sectors |
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Summary on Grant Application Form |
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This proposal concentrates on the development of an environmentally benign process, hydroformylation of higher olefins in scC02 by tailor-made rhodium catalysts, to produce more effectively long chain aldehydes/alcohols - important species for a range of commercial processes. Our aim is to investigate these reactions on a laboratory scale, determine the solubilities of the reactants and products, define the phase boundary of the multicomponent systems, and finally take the hydroformylation reaction to a small pilot plant to obtain realistic data for a full scale process design. The major benefits of the new process include 1) milder reaction conditions in comparison with the current cobalt-based process, 2) easy catalyst/product separation, and 3) minimal environmental impact. Exploratory study of the catalytic oxidation of higher olefins by 02 in scC02 will also be carried out. The catalytic processes will be developed in Liverpool, and the chemical engineering aspects of the hydroformylation developed in Leeds. This strongly interactive programme represents the very first example where the catalytic chemistry in scC02 is developed in conjunction with the development of the related process chemistry, and will thus provide an excellent opportunity for the UK to gain world-wide status in catalysis in supercritical fluids.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.liv.ac.uk |