Details of Grant 

EPSRC Reference:	GR/L84001/01
Title:	REORGANISATION DYNAMICS ACCOMPANYING CHARGE TRANSFER REACTIONS AND RELAXATION
Principal Investigator:	Phillips, Professor D
Other Investigators:	Toner, Mr W Toner, Mr W Parker, Professor AW Towrie, Professor M Matousek, Professor P
Researcher Co-Investigators:
Project Partners:
Department:	Chemistry
Organisation:	Imperial College London
Scheme:	Standard Research (Pre-FEC)
Starts:	01 November 1998	Ends:	31 October 2001	Value (£):	188,636
EPSRC Research Topic Classifications:	Gas & Solution Phase Reactions
EPSRC Industrial Sector Classifications:	No relevance to Underpinning Sectors
Related Grants:
Panel History:
Summary on Grant Application Form
We propose to use time resolved resonance Raman (TR3) investigations to further the fundamental understanding of the reaction dynamics in solution. This will use both Stokes and anti-Stokes spectroscopy and will involve the development of a 200 fs TR3 capability. The work will make detailed studies on the behavioural properties of newly excited molecules and how the ensuing structural perturbations are related to IVR, wavepacket dynamics, solvation and external energy disposal to the solvent bath. The way these processes are related can be decisive in determining the outcome of the activated chemical process and the work is relevant to many natural and synthetic process, particularly electron/proton transfer and intra-molecular transformations.
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Organisation Website:	http://www.imperial.ac.uk