| EPSRC Reference: |
GR/L80515/01 |
| Title: |
MONOCYCLIC MEDIUM-RING DIPHOSPHINES AS LIGANDS FOR CATALYSIS |
| Principal Investigator: |
Alder, Professor R |
| Other Investigators: |
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| Project Partners: |
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| Department: |
Chemistry |
| Organisation: |
University of Bristol |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 January 1998 |
Ends: |
30 June 2000 |
Value (£): |
93,849
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| EPSRC Research Topic Classifications: |
| Chemical Synthetic Methodology |
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| EPSRC Industrial Sector Classifications: |
| No relevance to Underpinning Sectors |
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Summary on Grant Application Form |
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We have recently developed novel synthetic routes to medium-ring diphosphines containing 8-, 9- and 10-membered rings and a range of substituents on phosphorus via diphosphabicycloalkanes. This versatile approach permits the preparation of pure cis-isomers of medium-ring diphosphines which are potentially valuable chelating ligands. The aims of this proposal are:1. To exploit this synthetic route to prepare a wide variety of medium-ring cis-diphosphines, including chiral examples.2. To examine their potential as ligands in comparison with standard chelating diphosphines.3. To develop applications involving the use of medium-ring cis-diphosphines in catalytic processes.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.bris.ac.uk |