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EPSRC Reference: GR/L58309/01
Title: IMPROVING THE PERFORMANCE OF CAPACITOR FERROELECTRICS BY THIN FILM MULTILAYER FABRICATION
Principal Investigator: Gregg, Professor J
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Messrs Avx/kyocera Northern Ireland Centre for Adv Material
Department: Sch of Mathematics and Physics
Organisation: Queen's University of Belfast
Scheme: Standard Research (Pre-FEC)
Starts: 10 June 1997 Ends: 09 June 2000 Value (£): 50,028
EPSRC Research Topic Classifications:
Materials Processing
EPSRC Industrial Sector Classifications:
Electronics
Related Grants:
Panel History:  
Summary on Grant Application Form
Property anomalies are often observed when materials undergo phase transformations. One such anomaly is the sharp increase in dielectric constant associated with perovskite ferroelectric materials at their Curie Point. Sharp temperature dependence means that the Curie Peak behaviour cannot be fully exploited in commercial capacitors. 'Relaxor' ferroelectrics are the exception. Nanoscale inhomogeneity in relaxors means that regions undergo Curie Point behaviour at different temperatures, broadening transformation and giving some level of temperature independent behaviour. Normally it would be expected that a broadening of the dielectric constant peak would correspond to a lowering in peak value, but in relaxors this is not the case. It is suspected that the reason for this is that inhomogeneities in relaxors occur on a nanoscale. It is proposed that relaxor behaviour be duplicated by fabricating thin film multilayers of different ferroelectric materials, reproducing nanoscale heterogeneity. The dielectric response of these thin multilayers will be compared to that of relatively thick film mixtures. The ability to fabricate 'artificial relaxors' would mean that some of the more rigorous industrial capacitor specifications could be met without sacrifice in dielectric constant.
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Organisation Website: http://www.qub.ac.uk