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Details of Grant 

EPSRC Reference: GR/L14404/01
Title: ROVIBRATIONAL ENERGY TRANSFER AND ROTATIONAL EFFECTS ON BIOMOLECULARREACTIONS
Principal Investigator: Smith, Professor I
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: School of Chemistry
Organisation: University of Birmingham
Scheme: Standard Research (Pre-FEC)
Starts: 01 July 1996 Ends: 30 June 1999 Value (£): 33,240
EPSRC Research Topic Classifications:
Physical Organic Chemistry
EPSRC Industrial Sector Classifications:
Related Grants:
Panel History:  
Summary on Grant Application Form
The experiments use an infrared-ultraviolet double resonance technique. Tunable pulses of IR radiation from an optical parametric oscillator (OPO) promote molecules to specific rovibronic levels and a tunable UV laser is used to follow the kinetics and pathways of relaxation via LIF techniques. The laser requested in this proposal is required to pump the dye laser providing the UV radiation. The basic double resonance method will provide information on the relaxation of HCN and C2H2. In parts (ii) and (iii), the behaviour of species created by pulsed photolysis either in unusually high rotational levels or in the presence of reactive collision partners will be examined.
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Organisation Website: http://www.bham.ac.uk