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Details of Grant 

EPSRC Reference: GR/L11045/01
Title: LIQUID LIQUID PHASE SEPARATION IN HOMOPOLYMER - COPOLYMER BLENDS
Principal Investigator: Barham, Professor PJ
Other Investigators:
Hill, Dr M Hanna, Dr S
Researcher Co-Investigators:
Project Partners:
Department: Physics
Organisation: University of Bristol
Scheme: Standard Research (Pre-FEC)
Starts: 01 March 1995 Ends: 31 August 1998 Value (£): 124,624
EPSRC Research Topic Classifications:
Materials Characterisation
EPSRC Industrial Sector Classifications:
Related Grants:
Panel History:  
Summary on Grant Application Form
We have pioneered research on homopolymer / lightly branched copolymer blends, where the physical properties of the two components are very similar. We have developed novel, indirect, methods to study liquid-liquid phase separation (LLPS) and have shown that in linear / lightly branched polyethylene blends LLPS is found, in the unusual form of a closed loop at low linear polymer content. We are now in a position to expand and exploit this research. Under SERC funding we will pursue three lines of study, all following from current work -* We will further the understanding of the novel LLPS we have identified, both through modelling and through experimentation on well defined systems.* We will develop experimental methods in order to observe LLPS directly in the melt.* We will extend the range of blends studied to include materials with higher branch densities, with branches which are chemically different from the backbone, and at a wide range of chemically different polymers.
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Organisation Website: http://www.bris.ac.uk