| EPSRC Reference: |
GR/K99336/01 |
| Title: |
HIGH RESOLUTION NMR OF QUADRUPOLAR NUCLEI IN SOLIDS WITHOUT THE REQUIREMENT FOR DOR OR DAS |
| Principal Investigator: |
Dupree, Professor R |
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| Department: |
Physics |
| Organisation: |
University of Warwick |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
15 May 1996 |
Ends: |
14 May 1998 |
Value (£): |
37,624
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Summary on Grant Application Form |
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The disadvantages of present techniques for reducing 2nd-order quadrupolar interactions in the solie-state NMR of I>0.5 nuclei can be removed by a new 2D technique. The 1st dimension is shift, and the second is the time evolution of a multiple-quantum coherence. By suitable manipulation these can render the quadrupolar lineshape orthogonal to the shift scale, with enhanced shift resolution. Successful development of this technique would greatly extend the applicability of NMR to eg. zeolites, polyoxometallates and metal-oxide based catalysts. An essential spectrometer upgrade is sought.Key Words: Physics, Chemistry, Materials, NMR, Solids, New Technique.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.warwick.ac.uk |