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Details of Grant 

EPSRC Reference: GR/K93563/01
Title: DIRECT ACTIVATION OF CAF2 TOWARDS HALOGEN EXCHANGE REACTIONS USING SUPERCRITICAL FLUIDS
Principal Investigator: Whyman, Dr R
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: University of Liverpool
Scheme: ROPA
Starts: 10 March 1997 Ends: 09 March 1999 Value (£): 94,046
EPSRC Research Topic Classifications:
Gas & Solution Phase Reactions
EPSRC Industrial Sector Classifications:
Related Grants:
Panel History:  
Summary on Grant Application Form
It is proposed to establish the scope of a recent discovery concerning the activation of CaF2 in supercritical CO2 towards chloride for fluoride exchange reactions in activated substituted aromatic hydrocarbons. We propose to explore the range of substrates, supercritical fluids and modifiers to which this is applicable, and to identify possible intermediates in the activation process using both conventional methods and MVS techniques.
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Organisation Website: http://www.liv.ac.uk