| EPSRC Reference: |
GR/K89023/02 |
| Title: |
ROPA COMPLEXES NEW PYRIDINE THIOLATE LIGANDS AND APPLICATIONS IN SMALL MOLECULE ACTIVATION CATALYSIS |
| Principal Investigator: |
Dilworth, Professor J |
| Other Investigators: |
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| Department: |
Oxford Chemistry |
| Organisation: |
University of Oxford |
| Scheme: |
ROPA |
| Starts: |
01 October 1997 |
Ends: |
30 June 2000 |
Value (£): |
43,960
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| EPSRC Research Topic Classifications: |
| Chemical Synthetic Methodology |
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| EPSRC Industrial Sector Classifications: |
| No relevance to Underpinning Sectors |
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Summary on Grant Application Form |
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Some new, tri- and bidentate 2-pyridine-arylthioilate or thioether ligands with N2S or NS donor sets and variable steric requirements will be synthesised. Their chemistry with Fe, Mo, W and Re hydrido-precursors will be investigated to prepare new sulphur-ligated hydrides capable of reaction with small molecules and catalysis. The Rh(I), Ir(I) and Pt(II) chemistry will also be explored and catalytic activity for carbonylation, hydrosilylation and hydroformylation assessed. Aromatic thiols with chiral substituents will be deployed for enantioselective catalysis. Zn(II) and Cu(I) complexes of chiral pyridine thiolates will be studied as catalysts for the enantioselective 1-4 addition of Grignards to cyclohexenone.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.ox.ac.uk |