| EPSRC Reference: |
GR/K52263/01 |
| Title: |
TETHERED ALKOXIDES IN CUPRATE CATALYSIS |
| Principal Investigator: |
Woodward, Professor S |
| Other Investigators: |
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| Department: |
Chemistry |
| Organisation: |
University of Hull |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 December 1995 |
Ends: |
30 November 1998 |
Value (£): |
6,283
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| EPSRC Research Topic Classifications: |
| Chemical Synthetic Methodology |
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Summary on Grant Application Form |
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This programme will investigate the properties of new kinds of organocuprate reagents containing ligands that are simultaneously able to stabilise copper (I) and the Lewis acid counter cation associated with a generalised cuprate M[RNTCuRT] (M = counter cation, Li, Mg, Al, etc; RNT = non-transferable group, SAr, PR2; RT = transferable organo function). Bidentate ligands of the types HO-bridge-SH and HO-bridge-PHR will engender organocuprate structures midway between traditional 'low order' and so called 'higher order' cuprates. The presence of a chiral bridge will allow use of these reagents in asymmetric copper-catalysed additions of organometallics to enone systems.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.hull.ac.uk |