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Details of Grant 

EPSRC Reference: GR/J02476/01
Title: DEVELOPMENT OF RAPID ENERGY-DISPERSIVE DIFFRACTION FOR KINETIC STUDIES ON NOVEL ZEOLITE/CEMENT MATERIALS
Principal Investigator: Barnes, Professor P
Other Investigators:
Researcher Co-Investigators:
Project Partners:
British Gas Castle Cement Schlumberger
Department: Biological Sciences
Organisation: Birkbeck College
Scheme: Standard Research (Pre-FEC)
Starts: 01 October 1993 Ends: 30 September 1996 Value (£): 86,343
EPSRC Research Topic Classifications:
Materials Characterisation
EPSRC Industrial Sector Classifications:
Construction Energy
Transport Systems and Vehicles Water
Related Grants:
Panel History:  
Summary on Grant Application Form
This project would commence with the designing and building of an in-situ energy-dispersive diffraction cell for studying zeolite synthesis and cement hydration: the specification would include a range of environmental possibilities (Atmospheric, autoclave, controlled gas-percolation, temperature control (0-250 C) and other facilities (sample spinning, remote controlled mixing etc.). The cell would be used to investigate:1) The kinetics of autoclave synthesis/cation exchange of experimental zeolites with potential for chosen gas-separation properties and2) The hydration mechanisms of selected cement types over temperatures from 80-200 C to simulate conditions of rapid curing.These dynamic experiments would be backed up by essential static characterisation studies, which for the zeolites would involve combined powder diffraction/EXAFS refinement of the cation sites. Similarly the crystalline phase composition and Fe-co-ordination in the glassy phases of the selected cements would be characterised to establish causative links with their varying hydration pattern. These combined studies would bring essential new insights to important problems in materials science that could not otherwise be studied.
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Further Information:  
Organisation Website: http://www.bbk.ac.uk/