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Details of Grant 

EPSRC Reference: GR/H74315/01
Title: ORIGINS OF AUTOIGNITION CENTRES IN END-GAS COMBUSTION
Principal Investigator: Griffiths, Professor J
Other Investigators:
Whitaker, Professor JBC Whitaker, Dr B Sheppard, Professor CGW
Researcher Co-Investigators:
Project Partners:
Department: Colour Chemistry
Organisation: University of Leeds
Scheme: Standard Research (Pre-FEC)
Starts: 18 September 1992 Ends: 17 June 1995 Value (£): 83,792
EPSRC Research Topic Classifications:
Combustion
EPSRC Industrial Sector Classifications:
Related Grants:
Panel History:  
Summary on Grant Application Form
The thermokinetic interactions that control hydrocarbon combustion in the temperature range 600 - 800 K (the range in which an overall negative temperature coefficient of reaction rate occurs) may cause the initiation of autoignition centres at points close to the wall of combustion chambers rather than in the hotter core gas. There is some support for this to be seen in high-speed films of autoignition under knocking conditions in si engines. The primary objectives of this project are to investigate the location of sites at which the cool flame and second-stage, hot ignition are first seen in the chamber of the rapid compression machine (RCM), how the locations of such sites are governed by the compression temperature and pressure of the reactants, and to explore the relevance to and potential impact on engine combustion. Supplementary studies of the corresponding, oscillatory two-stage ignition of hydrocarbon fuels in a low pressure, stirred flow reactor will yield more detailed chemical information on the spatially resolved development of autoignition in single cylinder engine and its relationship to engine-knock will be investigated by Mie scattering from multiple laser sheets. The combustion of butane and higher alkanes is to be studied.
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Organisation Website: http://www.leeds.ac.uk