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Details of Grant 

EPSRC Reference: GR/M94397/01
Title: IN-SITU ELECTROCHEMICAL SPM STUDIES OF METAL ENVIRONMENT INTERACTIONS
Principal Investigator: Ryan, Professor M
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Tata Steel Limited University of Otago
Department: Materials
Organisation: Imperial College London
Scheme: Standard Research (Pre-FEC)
Starts: 21 October 1999 Ends: 20 October 2002 Value (£): 50,085
EPSRC Research Topic Classifications:
Analytical Science Materials Characterisation
EPSRC Industrial Sector Classifications:
Manufacturing Electronics
Related Grants:
Panel History:  
Summary on Grant Application Form
The nature of metal oxide environment interfaces are poorly defined and a fundamental understanding of these interfaces is lacking in the literature. The proposed research encompasses the following elements: 1) characterisation the oxide solution interface for a given alloy/solution system 2) determination of the critical factors affecting pit initiation 3) adsorption characteristics of a range of industrially relevant chemicals on to passive metal surfaces. We plan to use in-situ STM and AFM to obtain atomic resolution imaging of oxide-covered metal surfaces under specific environmental conditions. These techniques will provide structural characterisation of the surface under investigation. and the surface response to electrochemical changes. We will systematically investigate the factors controlling pit initiation and surface adsorption in typical engineering systems.Additionally, traditional d.c. electrochemical and ac impedance measurements will be performed to quantify the underlying electrochemical mechanisms and corrosion resistance.
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Organisation Website: http://www.imperial.ac.uk