| EPSRC Reference: |
GR/M75174/01 |
| Title: |
SUBSTRATE ACTIVATION WITH RUTHENIUM CATALYSTS |
| Principal Investigator: |
Williams, Professor JM |
| Other Investigators: |
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| Department: |
Chemistry |
| Organisation: |
University of Bath |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 February 2000 |
Ends: |
31 January 2003 |
Value (£): |
52,290
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| EPSRC Research Topic Classifications: |
| Chemical Synthetic Methodology |
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| EPSRC Industrial Sector Classifications: |
| Chemicals |
Pharmaceuticals and Biotechnology |
| No relevance to Underpinning Sectors |
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Summary on Grant Application Form |
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The proposed research highlights the large difference in reactivity between alkenes adjacent to an alcohol or carbonyl functional group. Rapid, reversible interconversation between alcohols and carbonyls using transfer hydrogenation catalysts (mainly ruthenium) provides an interesting approach to catalysis. Conjugate addition and Diels Alder reactions will provide the basis for examining this catalytic activation. Additionally, similar reactions will provide a means for chemical transformation of alcohol and carbonyl groups. For example, the conversion of aldehydes into ketones is consider.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.bath.ac.uk |