| EPSRC Reference: |
GR/M68190/01 |
| Title: |
(ROPA) THE SYNTHESIS CHARACTERISATION AND COORDINATION CHEMISTRY OF NOVEL ARSENIC (III) LIGANDS |
| Principal Investigator: |
Pringle, Professor P |
| Other Investigators: |
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| Department: |
Chemistry |
| Organisation: |
University of Bristol |
| Scheme: |
ROPA |
| Starts: |
01 October 1999 |
Ends: |
30 September 2002 |
Value (£): |
199,819
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| EPSRC Research Topic Classifications: |
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| EPSRC Industrial Sector Classifications: |
| Chemicals |
No relevance to Underpinning Sectors |
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Summary on Grant Application Form |
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ROPA - This project is a fundamental study of new arsenic (III) ligands derived from two general reactions. Firstly, hydroarsination of C=O and C=C bonds with AsH3 or H2As(CH2)nAsH2 will give unusual tertiary arsines. For example, addition of AsH3 to formaldehyde will give a water-soluble tertiary arsine and addition of H2As(CH2)nAsH2 to acetylacetone will give adamantane-like cage arsines. Secondly, addition of biphenols to AsC13 or RasC12 will give cyclic arsenites and arsonites respectively which are classes of ligand hitherto unexplored. The co-ordination chemistry and catalysis with the new arsenic (III) ligands will be investigated.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.bris.ac.uk |