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Details of Grant 

EPSRC Reference: GR/M50591/01
Title: RADICAL CASACADE REACTIONS A COST PROGRAMME - U.K. CONTRIBUTION ON RADICAL-POLAR CROSSOVER REACTIONS
Principal Investigator: Murphy, Professor JA
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Pure and Applied Chemistry
Organisation: University of Strathclyde
Scheme: Standard Research (Pre-FEC)
Starts: 22 June 1999 Ends: 21 June 2001 Value (£): 18,058
EPSRC Research Topic Classifications:
Chemical Synthetic Methodology
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
Related Grants:
Panel History:  
Summary on Grant Application Form
This programme relates to a recently successful European Union (COST) application. The COST programme aims to extend the Chemistry of aliphatic radicals; my contribution to that will involve a study of the behaviour of aliphatic radicals under radical-polar crossover reaction conditions. Specifically, the alkyl radicals will be generated via fragmentation reactions of o-alkylthioethyl benzenediazonium salts. The studies will aim to uncover the ground-rules which govern the reactions of aliphatic radicals with TTF+ and related-cations.
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Organisation Website: http://www.strath.ac.uk