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Details of Grant 

EPSRC Reference: GR/M06239/01
Title: YIELDING, FLOW AND AGEING OF TEXTURED SOFT MATERIALS
Principal Investigator: Pusey, Professor P
Other Investigators:
Poon, Professor W Cates, Professor M
Researcher Co-Investigators:
Project Partners:
Unilever
Department: Sch of Physics and Astronomy
Organisation: University of Edinburgh
Scheme: Standard Research (Pre-FEC)
Starts: 01 January 1999 Ends: 31 December 2001 Value (£): 197,740
EPSRC Research Topic Classifications:
Complex fluids & soft solids Rheology
EPSRC Industrial Sector Classifications:
Chemicals Food and Drink
Related Grants:
Panel History:  
Summary on Grant Application Form
We request funding to study the yielding and ageing of a wide range of soft solids under (oscillatory) shear using a new method, diffusing-wave spectroscopy (DWS) echo. In this method, the degree of irreversible rearrangement a material suffers when stressed (i.e. the amount of plastic rather than elastic strain) is monitored precisely by correlating the intensity of light scattered before and after cycles of deformation in a purpose-built precision shear cell. We also proposed an extension of the method: by varying the degree of refractive-index matching and thus the scattering power of the sample, the spatial scale over which rearrangements are probed can be tuned. Materials to be investigated may include colloidal glasses and gels (dense and ramified amorphous packing of particles), and dense packings of viscoelastic particles (such as multilamellar surfactant vesicles, or onions ). Data obtained from other techniques, such as conventional and two-colour light scattering, rheology and microscopy, will be employed to complement the microdynamical information derived from DWS echo. This project should give improved understanding of the mechanisms of slow structural changes in a range of textured metastable states (soft solids), and therefore better prediction and control of shelf life in a range of industrial products.
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Organisation Website: http://www.ed.ac.uk