| EPSRC Reference: |
GR/L59399/01 |
| Title: |
POLYMER - SUPPORTED CARBONYLATION CATALYSTS |
| Principal Investigator: |
Sherrington, Professor DC |
| Other Investigators: |
|
| Researcher Co-Investigators: |
|
| Project Partners: |
|
| Department: |
Pure and Applied Chemistry |
| Organisation: |
University of Strathclyde |
| Scheme: |
LINK |
| Starts: |
01 October 1997 |
Ends: |
30 September 1999 |
Value (£): |
48,720
|
| EPSRC Research Topic Classifications: |
| Catalysis & Applied Catalysis |
|
|
| EPSRC Industrial Sector Classifications: |
|
| Related Grants: |
|
| Panel History: |
|
|
Summary on Grant Application Form |
|
The research project is broken down into 7 tasks. Task 1 is to develop an in-situ infra-red technique for observing rhodium catalyst species within the polymer support under reaction conditions. Task 2 is to correlate catalyst carbonylation behaviour with the nature and distribution of catalyst species between the polymer support and the bulk liquid. Task 3 is to identify the factors which control the strength of the catalyst-support ion pair interaction and determine their influence of catalysis. Task 4 is to quantify the distribution of all liquid and determine their influence on catalysis. Task 4 is to quantify the distribution of all liquid components between the polymer support phase and the bulk liquid phase. Task 5 is to design and synthesize optimized novel polymer supports based on the outcome of earlier tasks. Task 6 is to evaluate novel polymer-supported ion-paired rhodium catalysts in carbonylation. Task 7 is to explore the application of polymer-support ion-paired Rh catalysts in the hydroformylation of higher alk-l-enes. Task 1 will be led by the Sheffield parter; Task 2 by B.P.; Task 3 by Sheffield and J.M.; Tasks 4 and 5 Strathclyde; Task 6 B.P. and Task 7 by Strathclyde.
|
|
Key Findings |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
|
Potential use in non-academic contexts |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
|
Impacts |
|
| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
|
| Date Materialised |
|
|
|
|
Sectors submitted by the Researcher |
|
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
| Project URL: |
|
| Further Information: |
|
| Organisation Website: |
http://www.strath.ac.uk |