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Details of Grant 

EPSRC Reference: GR/L10352/01
Title: 'TOPOLOGICAL AUXILIARIES': A NOVEL STRATEGY FOR THE SYNTHESIS OF POLYROTAXANES
Principal Investigator: Leigh, Professor D
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Unknown
Organisation: UMIST
Scheme: Standard Research (Pre-FEC)
Starts: 01 November 1996 Ends: 30 September 1998 Value (£): 66,450
EPSRC Research Topic Classifications:
Materials Synthesis & Growth
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
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Summary on Grant Application Form
The aim of this proposal is to establish a general strategy for the synthesis of polyrotaxanes via topological auxiliaries. The strategy is based upon the solvent-dependent translational isomerism of rotaxanated monomer precursors which are prepared by hydrogen bond-mediated self-assembly processes discovered at UMIST. The structure-property relationship of the resulting polyrotaxanes will also be investigated.
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