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Details of Grant 

EPSRC Reference: GR/K91040/01
Title: TRANSPORT MECHANISMS OF SOLUTES IN GROUND-WATERS FROM PHYSICAL FRACTIONATION OF CL & BR STABLE ISOTOPES
Principal Investigator: Coleman, Professor ML
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Postgrad Research Inst for Sedimentology
Organisation: University of Reading
Scheme: ROPA
Starts: 01 October 1996 Ends: 31 December 1998 Value (£): 96,391
EPSRC Research Topic Classifications:
Assess/Remediate Contamination
EPSRC Industrial Sector Classifications:
Related Grants:
Panel History:  
Summary on Grant Application Form
Analyses of oil-field brines show unusual, extreme compositions of chlorine stable isotopes, believed to result from physical processes, e.g.diffusion. We will develop methods for isotopic analysis of both chlorine and bromine in dilute solution. Laboratory experiments will define chemical and isotopic changes resulting from diffusion, ion-exchange, osmosis and membrane filtration. The data will be compared with theoretical computations and used to interpret measurements from an accessible natural laboratory: a land-fill site where there is evidence of enhanced chloride transport. This will test if the methodology can characterise and quantify solute transport mechanisms in natural systems.
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Organisation Website: http://www.rdg.ac.uk