EPSRC Reference: |
GR/K90173/01 |
Title: |
SYNTHESIS IN CARBON DIOXIDE |
Principal Investigator: |
Holmes, Professor AB |
Other Investigators: |
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Researcher Co-Investigators: |
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Project Partners: |
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Department: |
Chemistry |
Organisation: |
University of Cambridge |
Scheme: |
ROPA |
Starts: |
26 March 1997 |
Ends: |
25 September 1998 |
Value (£): |
46,790
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EPSRC Research Topic Classifications: |
Chemical Synthetic Methodology |
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EPSRC Industrial Sector Classifications: |
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Related Grants: |
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Panel History: |
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Summary on Grant Application Form |
The profound solvent power of carbon dioxide in the supercritical (and in the liquid) state will be explored with regard to the potential added value of organic synthesis in this medium. The scope of the following classes of reactions will be investigated: 1) 1, 3-Dipolar cycloaddition reactions; 2) Transition metal-catalysed oxidations with dioxygen; 3) Oxidation reactions with hydrogen peroxide and derivatives; 4) Mukaiyama Lewis acid-catalysed aldol and Michael reactions; 5) Metathesis and ring closing reactions. Asymmetric synthesis will feature heavily in the studies.
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Key Findings |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
Summary |
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Date Materialised |
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Sectors submitted by the Researcher |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Project URL: |
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Further Information: |
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Organisation Website: |
http://www.cam.ac.uk |