EPSRC logo

Details of Grant 

EPSRC Reference: GR/K21399/01
Title: ULTRAFAST THIRD ORDER NONLINEARITIES AND PHOTOREFRACTIVE STUDIES OF ORGANIC ZWITTERION MATERIALS
Principal Investigator: Kar, Professor AK
Other Investigators:
Wherrett, Professor B
Researcher Co-Investigators:
Project Partners:
Department: Physics
Organisation: Heriot-Watt University
Scheme: Standard Research (Pre-FEC)
Starts: 01 October 1994 Ends: 30 September 1996 Value (£): 88,324
EPSRC Research Topic Classifications:
Materials Characterisation
EPSRC Industrial Sector Classifications:
Related Grants:
Panel History:  
Summary on Grant Application Form
The Zwitterion materials DEMI and its analogues are currently synthesised at the University of Durham and have demonstrated high dipole-moments and hyperpolarizabilities. The ultrafast third-order non-linearity of organic materials has been shown to increase approximately linearly with the second order non-linearity in donor-pi-acceptor molecules, which makes DEMI series specially attractive since the off-resonance second order hyperpolarizability is among the largest of those measured. We shall use subpicosecond laser techniques to make a comparative study. The same material may be doped easily into polymer films to produce photorefractive materials, which property we shall also study for a range of laser-pulse timescales. The main advantage in using DEMI and its analogues in the latter application area is that large in plane electro-optic coefficients are available for use. This is vital in demonstrating devices of practical value.
Key Findings
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
Potential use in non-academic contexts
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
Impacts
Description This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
Summary
Date Materialised
Sectors submitted by the Researcher
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
Project URL:  
Further Information:  
Organisation Website: http://www.hw.ac.uk