| EPSRC Reference: |
GR/K01728/01 |
| Title: |
INTER AND INTERMOLECULAR ASYMMETRIC OXIDATIONS WITH C2 CHIRAL & CARBOHYDRATE DIOXIRANES |
| Principal Investigator: |
Gardiner, Dr JM |
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| Department: |
Chemistry |
| Organisation: |
UMIST |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
17 June 1994 |
Ends: |
16 June 1997 |
Value (£): |
6,097
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Summary on Grant Application Form |
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1. Synthesis, isolation, characterisation of a range of novel C2 and carbohydrate derived chiral dioxiranes from appropriate chiral ketones.2. Asymmetric oxidations with these reagents of prochiral acyclic, cyclic, and heterosubstituted prochiral alkenes or sulphide functionalities, and development of chiral dioxirane auxiliaries.3. Mechanistic investigation of stereochemistry of dioxirane oxygen atom transfer to heteroatoms (eg P) , using stereochemically unambiguous substrates.
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Key Findings |
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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