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Details of Grant 

EPSRC Reference: EP/M507726/1
Title: Photo-responsive graphene for anti-corrosive and conductive strong, compliant silicone nanocomposites
Principal Investigator: Bilotti, Dr E
Other Investigators:
Gautrot, Professor JE
Researcher Co-Investigators:
Project Partners:
Department: School of Engineering & Materials Scienc
Organisation: Queen Mary University of London
Scheme: Technology Programme
Starts: 01 October 2015 Ends: 30 September 2016 Value (£): 88,337
EPSRC Research Topic Classifications:
Materials Processing Materials Synthesis & Growth
EPSRC Industrial Sector Classifications:
Aerospace, Defence and Marine
Related Grants:
Panel History:  
Summary on Grant Application Form
Graphene is an ultra-thin carbon-based material that is constituted of a single layer of carbon atoms arranged into a two

dimensional sheet. It displays exceptional heat and electron conduction properties. Graphene also has a high potential for

anti-corrosion properties as it displays ultra-high resistance to the diffusion of gases and small molecules and due to its

excellent stability towards oxidation. However, graphene suffers from the drawback of being poorly soluble/dispersible in

polymer matrices and hard to process, unless stabilisers are used. Unfortunately, although the use of stabilisers leads to

improve processability, it also decreases the performance of graphene based nanocomposites.

This project aims to develop a novel approach for the stabilisation of graphene using a type of smart ultra-thin graphene

surface functionalisation, termed polymer brush. In particular, we will design polymer brushes that can be cleaved from the

graphene surface by irradiation with light, hence enabling their use to improve the processing of graphene without impairing

its exceptional heat and electrical conduction and anti-corrosion properties. This technology could have a considerable

impact on the application of graphene to a wide range of technologies.

In collaboration with FormFormForm Ltd., the company behind the range of silicone-based resins called Sugru, we will

explore the use of these materials to generate heat and electrically conductive silicone based matrices, as well as the

application of such composites as anti-corrosion coatings. Achieving high performance for such flexible silicone-based

composites, thanks to the exceptional properties of graphene, could open up a wide range of applications for such siliconebased

materials. Hence we will explore the use of this new technology to address some of the current challenges in the

manufacturing industry.
Key Findings
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Potential use in non-academic contexts
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Impacts
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Summary
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