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Details of Grant 

EPSRC Reference: EP/L022192/1
Title: Photosynthesis-inspired manufacturing of metal patterns (photobioform)
Principal Investigator: Desmulliez, Professor M
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Merlin Circuits
Department: Sch of Engineering and Physical Science
Organisation: Heriot-Watt University
Scheme: Standard Research - NR1
Starts: 30 April 2014 Ends: 29 October 2015 Value (£): 173,061
EPSRC Research Topic Classifications:
Electrochemical Science & Eng. Manufacturing Machine & Plant
Materials Processing
EPSRC Industrial Sector Classifications:
Electronics
Related Grants:
EP/L022133/1
Panel History:
Panel DatePanel NameOutcome
13 Nov 2013 Manufacturing with Light Interviews : 13 & 14 November 2013 Announced
Summary on Grant Application Form
We have invented a new patterning process, which allows the formation of metal tracks onto non-conductive, plastic, flexible substrates, coating or powder such as polyimide or PEI (polyetherimide).

The process takes place in air environment at atmosphere pressure using low cost equipment.

The process involves the simple dipping of a substrate into a solution of potassium hydroxide, following by another dipping into a metal ions solution. The first dipping allows the opening of the imide ring chemical structure and insertion of the potassium ions into the broken chemical ring. The second dipping allows the swapping of the potassium ions with the ions of the electrolyte solution.

A laser or a flood exposure equipment using a photomask can be used to reduce the surface metal ions resulting in a gradient of metal ions, then the ions diffuse into the depleted zone and reach the surface where they reduce. A mild electron-donating agent has been used to accelerate the reduction of the ions. A thin layer of metal nanoparticles is then formed using this simple process, which can be used for subsequent electroless plating or for sensing purposes. Our preliminary feasibility studies published in IEEE transactions in Nanotechnology have demonstrated the concept using a synthetic agent at the cost of long exposure time and damage to the substrate.

We started using a bio-inspired material, chlorophyll extracted from spinach leaves, to speed up the photochemical process from 3 hours to 1 minute exposure using a blue light LED. We wish demonstrate that the use of chlorophyll can enable a truly manufacturing process that can be scaled up, and fully characterised for plastic electronics, PVs, moulded interconnects in electronics, sensing applications, in conjunction with additive manufacturing for multi-material manufacturing.
Key Findings
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Organisation Website: http://www.hw.ac.uk