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Details of Grant 

EPSRC Reference: EP/J011053/1
Title: Late Transition Metal Hydroxide in Homogeneous Catalysis
Principal Investigator: Nolan, Professor SP
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: University of St Andrews
Scheme: Standard Research
Starts: 01 May 2012 Ends: 30 April 2015 Value (£): 671,286
EPSRC Research Topic Classifications:
Catalysis & Applied Catalysis Co-ordination Chemistry
EPSRC Industrial Sector Classifications:
Chemicals
Related Grants:
Panel History:
Panel DatePanel NameOutcome
08 Feb 2012 EPSRC Physical Sciences Chemistry - February 2012 Announced
Summary on Grant Application Form
The development of catalytic methods leading to little or no waste is an area of crucial importance in terms of energy and materials economy. The present proposal presents strategies to assemble complex molecular architectures or value-added compounds using simply synthesized organometallic complexes. The proposal adopts a two-prong approach. On the one side the design and synthesis of organometallic catalysts are proposed and on the other, some of the catalysts already synthesized by our group and the novel ones proposed will be tested in important greener chemical transformations. The catalytic activity of these well-defined complexes range from C-H bond functionalisation using CO2 to fluorine sources. The aims of the proposal are to develop and understand useful synthetic tools and methods, readily transferable to synthetic chemists, permitting facile protocols enabling the synthesis of complex molecular assemblies using plentiful under-utilised resources such as CO2 and C-H bonds.
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Organisation Website: http://www.st-and.ac.uk