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Details of Grant 

EPSRC Reference: EP/H024034/1
Title: Microporous materials based on Organic Molecules of Intrinsic Microporosity
Principal Investigator: McKeown, Professor N
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: Cardiff University
Scheme: Standard Research
Starts: 01 June 2010 Ends: 31 May 2013 Value (£): 324,136
EPSRC Research Topic Classifications:
Catalysis & Applied Catalysis Chemical Synthetic Methodology
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
Related Grants:
Panel History:
Panel DatePanel NameOutcome
01 Dec 2009 Physical Sciences Panel - Chemistry Announced
Summary on Grant Application Form
It will be established that rigid organic molecules of concave shapes pack space very inefficiently resulting in microporous materials. This concept will be explored by linking components of well-defined shape (trigonal, cruciform, tetrahedral and octahedral) via fused rings to prepare Organic Molecules of Intrinsic Microporosity (OMIMs), which are predicted to possess a unique combination of properties (microporosity, tailorability, homogenenity, solubility in organic solvents, relatively small molecular size, fluorescence, etc.). The concept will be extended to the preparation of dendrimers derived from similar conponents and assembled using the same chemistry. It is anticipated that some of these discrete, highly defined, molecules will form organic microporous materials of surface areas in excess of 1000 m2/g as determined by gas adsorption. A network of collaborators will explore the physical properties of the OMIMs and assess their potential for a number of applications.
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Organisation Website: http://www.cf.ac.uk