EPSRC Reference: |
GR/R05802/01 |
Title: |
Catalysis At Leicester - Multidisciplinary Catalysis Test Facility |
Principal Investigator: |
Hope, Professor E |
Other Investigators: |
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Researcher Co-Investigators: |
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Project Partners: |
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Department: |
Chemistry |
Organisation: |
University of Leicester |
Scheme: |
JREI |
Starts: |
12 July 2001 |
Ends: |
11 July 2004 |
Value (£): |
98,666
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EPSRC Research Topic Classifications: |
Catalysis & Applied Catalysis |
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EPSRC Industrial Sector Classifications: |
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Related Grants: |
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Panel History: |
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Summary on Grant Application Form |
A dedicated catalyst test facility is sought to investigate:(i) Fluorous bi-phase catalysis: mechanistic studies; evaluate reactivity/selectivity of fluorous-soluble catalyst systems for hydroformylation and asymmetric hydrogenation. To assess the benefits of separation of catalyst recovery under industrially relevant conditions.(ii) Supercritical hydrofluorocarbon (HFC) solvents: To measure and quantity the solvent properties of a range of supercritical fluids as novel solvent media. To examine the effects of reactants on solvent properties and how clustering is effected by pressure.(iii) Polymer-heterogenised homogeneous catalysts: To investigate the use of tailored polystyrene resins as catalyst support materials in industrially important heterogenised olefin polymerisation reactions.(iv) Development of new activators and precatalysts for olefin polymerisation: Test and evaluate new activators and precatalysts under high pressure conditions for olefin homo- and co-polymerisation.
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Key Findings |
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Potential use in non-academic contexts |
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Impacts |
Description |
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Summary |
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Date Materialised |
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Sectors submitted by the Researcher |
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Project URL: |
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Further Information: |
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Organisation Website: |
http://www.le.ac.uk |